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Updated: Dec 1, 2025

Development of a 3D Graphene Electrode Dielectrophoretic Device
Published on: June 22, 2014
Inherent Impurities in Graphene/Polylactic Acid Filament Strongly Influence on the Capacitive Performance of
Kalyan Ghosh1, Siowwoon Ng1, Christian Iffelsberger1
1Future Energy and Innovation Laboratory, Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200, Brno, Czech Republic.
Abstract:
Additive manufacturing or 3D-printing have become promising fabrication techniques in the field of electrochemical energy storage applications such as supercapacitors, and batteries. Of late, a commercially available graphene/polylactic acid (PLA) filament has been commonly used for Fused Deposition Modeling (FDM) 3D-printing in the fabrication of electrodes for supercapacitors and Li-ion batteries. This graphene/PLA filament contains metal-based impurities such as titanium oxide and iron oxide. In this study, we show a strong influence of inherent impurities in the graphene/PLA filament for supercapacitor applications. A 3D-printed electrode is prepared and subsequently thermally activated for electrochemical measurement. A deep insight has been taken to look into the pseudocapacitive contribution from the metal-based impurities which significantly enhanced the overall capacitance of the 3D-printed graphene/PLA electrode. A systematic approach has been shown to remove the impurities from the printed electrodes. This has a broad implication on the interpretation of the capacitance of 3D-printed composites.

