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Updated: Nov 30, 2025

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
Published on: October 31, 2019
Tuning Nonlinear Optical Behavior by Incorporation of the Chalcogenophene into Twistacenes
Yanbing Han1, Jinchong Xiao2, Xingzhi Wu3
1Department of Physics, Harbin Institute of Technology, Harbin 150001, P. R. China.
Abstract:
Four chalcogenophene-fused acenes containing O, S, Se, or Te, respectively, were presented, and the chalcogenophene effect on linear and nonlinear optics was systematically investigated. Their excited-state absorption performance and two-photon absorption (TPA) capacity could be modulated by the incorporating chalcogen atoms. The experimental results showed that the heavy chalcogen facilitated the intersystem crossing resulting in the presence of the triplet state absorption for PyPSe and PyPTe, and the TPA capacity gradually increased with the atomic size of the chalcogens. The theoretical calculation inferred that their nonlinear optical performance was closely related to the contributions of the chalcogenophene component to heterotwistacenes in the final excited state. In addition, PyPTe was able to work under various laser pulses from femtoseconds to nanoseconds.
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