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Published on: February 27, 2019
Multicolor Circularly Polarized Luminescence from Chiral Twistarenes
Yi Che1, Sujuan Wang1, Bihan Leng1
1College of Chemistry and Materials Science, Key Laboratory of Chemical Biology of Hebei Province, Hebei Research Center of the Basic Discipline of Synthetic Chemistry, Hebei University, Baoding 071002, P. R. China.
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Three novel arenes 4, 6, and 8 that emit blue, green, and red circularly polarized luminescence have been strategically synthesized through postfunctionalization of substituted twisttetracene. These compounds were thoroughly characterized through NMR and mass spectrometry, with the molecular structures of 8S and 8R being verified by single-crystal X-ray diffraction analysis. Furthermore, we successfully achieved white-light generation by precisely controlling the ratio of compounds 4, 6, and 8.
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