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Cyclohexane Vibrations: High-Resolution Spectra and Anharmonic Local Mode Calculations

Peter F Bernath1, Edwin L Sibert Iii2

  • 1Department of Chemistry and Biochemistry, Old Dominion University, Norfolk, Virginia 23529, United States.

The Journal of Physical Chemistry. A
|November 19, 2020
PubMed
Summary

High-resolution infrared spectra reveal complex vibrational interactions in cyclohexane. Anharmonic local mode calculations explain how CH2 scissor modes perturb C-H stretching, organizing molecular energy levels.

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