Electrochemical removal of RRX-3B in residual dyeing liquid with typical engineered carbonaceous cathodes

Electro-catalytic activities of carbonaceous cathodes including graphite plate, graphite felt, carbon felt, activated carbon felt (ACF) and carbon fiber felt (CFF) for degradation of Reactive Red X-3B (RRX-3B) in residual dyeing liquid were compared. The best electrochemical performance was obtained using dimensional stable anode (DSA) and CFF cathode due to the higher capacity for electro-generation of H₂O₂ by selective two-electron oxygen reduction. The CFF/DSA electrolysis system realized 78.2% COD removal and complete decolorization over a wide pH range. The efficacy of RRX-3B degradation was found to be dependent on the nature of carbonaceous materials. Electrochemical measurements showed that CFF possessed higher electrochemical surface area and hydrogen evolution reaction over-potential. Furthermore, the intrinsic graphitic N in CFF was proved to be catalytic active site by DFT calculations. Reactive Red X-3B degradation intermediates with benzene structures and carboxylic acids via hydroxylation in RRX-3B oxidation were identified by GC-MS. It was found that S/Cl/N-containing groups in RRX-3B molecule were mineralized to SO₄^2-, NO₃^- and Cl^- ions in the electrolysis.