River water treatment using electrocoagulation for removal of acetaminophen and natural organic matter

Electrocoagulation (EC) was assessed for removal of acetaminophen and natural organic matter (measured as UV₂₅₄) from river water. Process was assessed for time, electrode materials, inter electrode distance, and voltage. Best conditions for removal of acetaminophen and UV₂₅₄ absorbance were 60 min reaction time, aluminum-aluminum electrodes, 2 cm inter electrode distance, and 9 V. Acetaminophen tested at 1, 2, 5, 10, and 20 mg L^-1 showed that treatment efficiency decreased as the concentration increased. The main mechanism for removal of acetaminophen was H bonding with Al(OH)₃ flocs; this was confirmed by XRD and FT-IR spectrum. Pseudo-second order kinetics model exhibited a good fit on experimental data for acetaminophen removal at different concentrations. Univariate ANOVA indicated statistically significant difference between treatments for acetaminophen removal (F_2.76 = 136, P = <0.001). A significant linear correlation was found between UV₂₅₄ absorbance and acetaminophen removal at different concentrations. Preliminary analysis suggest that EC will cost US$ 0.22/m³ for river water treatment. The lab-scale EC process was compared with a full-scale water treatment plant for removal of natural organic matter. Water treatment plant after multiple levels of purification was not able to fully remove UV₂₅₄ absorbance whereas EC treatment showed good efficiency.