Delayed Fluorescence from Carbon Nanotubes through Singlet Oxygen-Sensitized Triplet Excitons

Single-wall carbon nanotubes (SWCNTs) in liquid suspension have been observed to emit delayed, microsecond-scale fluorescence arising from upconverted triplet excitons that are directly created through energy transfer from singlet oxygen molecules (¹O₂). The singlet oxygen is produced through quenching of an optically excited organic sensitizer. The mechanism of this delayed fluorescence has been deduced from measurements of time-resolved emission kinetics, delayed emission spectra, and polarization-resolved excitation-emission spectra. The observed strong dependence of ¹O₂ sensitization efficiency on SWCNT structure suggests that (7,6) triplet excitons have an energy near 970 meV. The yields for E₁₁ → E₁₁ upconversion are found to be in the range of several percent. These yields increase with increasing temperature and decrease with increasing excitation intensities, reflecting thermal activation and triplet-triplet exciton annihilation processes.