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BTEX compounds leachates from cigarette butts into water environment: A primary study
Sina Dobaradaran1, Torsten C Schmidt2, Wiebke Kaziur-Cegla3
1Systems Environmental Health and Energy Research Center, The Persian Gulf Biomedical Sciences Research Institute, Bushehr University of Medical Sciences, Bushehr, Iran; Department of Environmental Health Engineering, Faculty of Health and Nutrition, Bushehr University of Medical Sciences, Bushehr, Iran; Instrumental Analytical Chemistry and Centre for Water and Environmental Research (ZWU), Faculty of Chemistry, University of Duisburg-Essen, Universitätsstr. 5, Essen, Germany.
Cigarette butts leach toxic BTEX chemicals into water. While benzene levels were below guidelines, the overall threat to aquatic life and humans from littered cigarette butts remains significant.
Area of Science:
- Environmental Chemistry
- Ecotoxicology
- Water Quality Assessment
Background:
- Cigarette butts (CBs) are a major environmental pollutant, containing toxic chemicals like BTEX (benzene, toluene, ethylbenzene, o-xylene, and p-xylene).
- Potential risks of these chemicals to aquatic ecosystems and organisms are not fully understood due to a lack of systematic studies on their leaching behavior.
Purpose of the Study:
- To investigate the leaching concentrations of BTEX compounds from CBs into deionized water (DW) and river water (RW) for the first time.
- To assess the impact of contact time and water type on BTEX leaching and compare results with environmental guidelines.
Main Methods:
- Collected water samples (DW and RW) exposed to CBs over various contact times (15 minutes to 1 day).
- Quantified BTEX compound concentrations in leachate using analytical techniques.
- Analyzed the effect of contact time and water type on BTEX levels and compared them to Water Framework Directive (WFD) guidelines.
Main Results:
- BTEX compounds were detected in both DW and RW at all tested contact times, with toluene showing the highest and o-xylene the lowest mean concentrations.
- Leachate concentrations of BTEX compounds decreased significantly with time after smoking, with benzene, toluene, and ethylbenzene showing rapid reductions within 15 minutes.
- No significant differences in BTEX leachate levels were observed between DW and RW samples.
Conclusions:
- Leaching of BTEX compounds from cigarette butts into water bodies is confirmed, posing a potential risk to aquatic life.
- While leached benzene concentrations may not exceed WFD guidelines, the cumulative impact of littered CBs and their other toxic constituents warrants concern.
- Further research is essential to fully understand the ecotoxicological effects of CB leachates and inform effective pollution control strategies.
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