Scalable crystalline porous membranes: current state and perspectives

Crystalline porous materials (CPMs) with uniform and regular pore systems show great potential for separation applications using membrane technology. Along with the research on the synthesis of precisely engineered porous structures, significant attention has been paid to the practical application of these materials for preparation of crystalline porous membranes (CPMBs). In this review, the progress made in the preparation of thin, large area and defect-free CPMBs using classical and novel porous materials and processing is presented. The current state-of-the-art of scalable CPMBs with different nodes (inorganic, organic and hybrid) and various linking bonds (covalent, coordination, and hydrogen bonds) is revealed. The advances made in the scalable production of high-performance crystalline porous membranes are categorized according to the strategies adapted from polymer membranes (interfacial assembly, solution-casting, melt extrusion and polymerization of CPMs) and tailored based on CPM properties (seeding-secondary growth, conversion of precursors, electrodeposition and chemical vapor deposition). The strategies are compared and ranked based on their scalability and cost. The potential applications of CPMBs have been concisely summarized. Finally, the performance and challenges in the preparation of scalable CPMBs with emphasis on their sustainability are presented.