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Biomimetic Boroxine-Based Multifunctional Thermosets via One-Pot Synthesis
Xi Yang1, Meiling Guo1, Yuanpeng Wu1,2
1The Center of Functional Materials for Working Fluids of Oil and Gas Field, School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China.
Abstract:
Boroxine-based thermosets with remarkable mechanical tunability, self-healing ability, recyclability, and adhesive strength are of significant importance in various applications. However, complex multistep reactions are often required to prepare such thermosets. Herein, a facile one-pot approach to synthesize boroxine-based malleable thermosets is proposed. Random copolymers with pendant boronic acid groups were synthesized from alkenyl monomers containing boronic acids [4-vinylphenylboronic acid (4-VPBA), 3-vinylphenylboronic acid, or 3-acrylamidophenylboronic acid] and octadecanoxy polyethylene glycol methacrylate. Then, the as-prepared copolymers were cured to form thermosets with boroxine bonds. The tensile strengths of the thermosets were tailored to range from 9.3 to 27.5 MPa by increasing the concentration of 4-VPBA. Moreover, because of the reversible nature of dynamic boroxine bonds (transformation between boroxines and boronic acids) induced by water, the thermosets exhibit remarkable self-healing efficiency (up to 99%), tunable mechanical properties, and excellent recyclability. Additionally, the thermosets also demonstrate superior adhesive strength (as high as 73.9 MPa) on different substrates.
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