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A Combined Exponential-Power-Law Method for Interconversion between Viscoelastic Functions of Polymers and
Vitor Dacol1, Elsa Caetano1, João R Correia2
1CONSTRUCT (ViBEST), Faculty of Engineering (FEUP), University of Porto, 4200-465 Porto, Portugal.
This study simplifies determining polymer viscoelastic properties. It presents a new method to calculate relaxation modulus from creep tests, reducing experimental costs and effort for materials science applications.
Area of Science:
- Materials Science
- Polymer Science
- Mechanical Engineering
Background:
- Viscoelastic behavior of polymers is crucial for long-term mechanical applications.
- Characterizing viscoelasticity traditionally requires separate creep and relaxation tests.
- Existing methods for interconverting creep and relaxation data can be complex.
Purpose of the Study:
- To review methods for interconverting creep compliance and relaxation modulus.
- To introduce a novel, approximate interconversion scheme.
- To demonstrate the accuracy and applicability of the new method.
Main Methods:
- Review of existing time-domain interconversion techniques.
- Development of a new approximate interconversion scheme using Laplace transform and approximated Gamma function.
- Validation using diverse experimental data from scientific literature.
Main Results:
- The relaxation modulus can be accurately derived from creep compliance data.
- The proposed method offers ease of implementation and broad applicability.
- Experimental data confirms the accuracy of the new interconversion scheme.
Conclusions:
- The new method simplifies the determination of viscoelastic properties for polymers.
- It enables obtaining relaxation modulus from less costly creep tests.
- This approach is valuable for modeling polymer behavior under various mechanical loads.
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