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Electrooxidative B-H Functionalization of nido-Carboranes

Meng Chen1, Deshi Zhao1, Jingkai Xu1

  • 1State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210023, China.

Angewandte Chemie (International Ed. in English)
|December 29, 2020
PubMed
Summary

A new electrochemical method enables direct B-H functionalization of nido-carboranes. This green approach avoids metal catalysts and efficiently couples nido-carboranes with various heteroatoms, facilitating drug motif incorporation.

Keywords:
cage compoundscross-couplingelectrochemistryheterocyclessynthetic methods

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