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Updated: Nov 23, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Electrifying Sustainability on Transition Metal-Free Modes: An Eco-Friendly Approach for the Formation of C-N Bonds
Neha Dagar1, Partha Pratim Sen1, Sudipta Raha Roy1
1Department of Chemistry, Indian Institute of Technology Delhi, Indian Institute of Technology Delhi, Hauz Khas, New Delhi, 110016, India.
Abstract:
Embracing sustainable green methodologies and techniques in chemical transformations has always been in the limelight to the synthetic community. Electrosynthesis has emerged as a powerful, sustainable synthetic tool for molecular synthesis exploiting inexpensive electricity in place of sacrificial chemical oxidizing/reducing reagents. Herein, recent advances in the incorporation of transition metal-free redox mediators in electrosynthesis for the construction of C-N bonds are outlined. Furthermore, conjugation of this strategy with flow catalysis allows easy scale up of the synthesis of molecular assembly. This comprehensive Review provides an overview of metal-free mediated electro-construction of C-N bonds, focusing on the reaction mechanisms involved and its synthetic applications.
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