[Spatial Distribution, Contamination Assessment, and Sources of Heavy Metals in the Urban Green Space Soils of a City in North China]

To study the condition of urban green space soils in the central parts of a city in North China, the spatial distribution, sources, and pollution levels of heavy metals (Cd, Hg, As, Pb, Cr, Cu, Zn, and Ni) within green space soils in the central urban districts of the city were investigated. The results showed that the soil quality was high overall. The mean concentrations of Cd, Hg, As, Pb, Cr, Cu, Zn, and Ni were 0.172, 0.202, 9.02, 34.7, 57.0, 31.2, 85.7, and 26.3 mg·kg^-1, respectively. The mean concentrations of Cd, Hg, Pb, and Zn in urban soils exceeded the background value of the Beijing-Tianjin-Tangshan region. All of the samples' heavy metal concentrations were lower than the risk screening values for soil contamination of development land in the national soil environment quality standards. With respect to the spatial distribution, the concentrations of As, Cr, and Ni were higher in the northwest of the study area, the concentrations of Cd and Zn were higher in the northeast, and the concentrations of Hg, Pb, and Cu were higher in the urban core area. As for the different land use types of the soils, the concentrations of Cd, Zn, and Ni were higher in the enterprise soils, while the concentrations of Hg, Pb, and Cu were higher in park and residential soils. Assessments of soil quality showed that 97.2% of soil samples' Nemerow integrated indices were less than 1, indicating that the soils were clean. Indices of potential ecological risk for all soil samples were less than 80, indicating that they posed a slight ecological risk. Multivariate statistical analysis (correlation and principle component analyses) showed that Cu, Pb, and Hg may originate from an anthropogenic source via the painting of ancient buildings and pesticides used to protect ancient trees. Chromium may originate from natural sources via geochemical activity and soil parent material; Cr, Zn, Ni, and As were derived from mixed sources through human and geochemical activities. The receptor model was used for identification and apportionment of pollution sources of elements over the standard. The contribution rates of sources were as follows:source 2(46.1%), source 3(33.1%), source 1(17.7%), and others (3.1%) for Cd, source 1(93.0%) for Cu, source 1(52.4%), source 3(24.2%), source 2(20.0%), and others (3.4%) for Zn, source 1(56.3%), source 2(37.8%), and source 3(5.8%) for Ni. Sources 1 and 3 were anthropogenic, while source 2 was natural.