GdFeO₃ Perovskite Oxide Decorated by Group X Heterometal Oxides and Bifunctional Oxygen Electrocatalysis

Bifunctional electrocatalysts for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are necessary in the renewable energy systems. However, the kinetically slow and large energy-demanding procedures of oxygen electrocatalysis make the preparation of bifunctional catalysts difficult. In this work, we report a novel hierarchical GdFeO₃ perovskite oxide of a spherelike nanostructure and surface modification with the group X heterometal oxides. The nanostructured GdFeO₃ layer behaved as a bifunctional electrocatalyst in the oxygen electrocatalysis of OER and ORR. Moreover, the surface decoration with catalytically active PtO + Ni/NiO nanoparticles enhanced the electrocatalytic performances substantially. Incorporation of mesoporous PtO + Ni/NiO nanoparticles into the porous GdFeO₃ nanostructure enlarged the electrochemically active surface area and provided the interconnected nanostructures to facilitate the OER/ORR. The nanostructures were visualized by scanning electron microscopy and transmission electron microscopy images, and the surface area and pore size of nanoparticles were analyzed from N₂ adsorption/desorption isotherms. Tafel analysis indicates that surface modification effectively improves the kinetics of oxygen reactions and accordingly increases the electrocatalytic efficiency. Finally, the 2 wt % PtO + NiO|GdFeO₃ (x = 0, 1, and 2) electrode achieved the enhanced OER performance with an overpotential of 0.19 V at 10 mA/cm² in an alkaline solution and a high turnover frequency of 0.28 s^-1 at η = 0.5 V. Furthermore, the ORR activity is observed with an onset potential of 0.80 V and a half-wave potential (E_1/2) of 0.40 V versus reversible hydrogen electrode.