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Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Top-Down Heterogeneous Colloidal Engineering Using Capillary Assembly of Liquid Particles.

Cicely Shillingford1, Brandon M Kim1, Marcus Weck1

  • 1Molecular Design Institute and Department of Chemistry, New York University, New York, New York 10003, United States.

ACS Nano
|January 13, 2021
PubMed
Summary
This summary is machine-generated.

Capillary assembly of liquid particles (CALP) is a novel microfabrication technique. This method engineers diverse, complex polymer colloids with unique shapes and functionalities for advanced materials.

Keywords:
Janus particlescapillary assemblycolloidsliquid particlespatchy particles

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Area of Science:

  • Materials Science
  • Colloid Science
  • Microfabrication

Background:

  • Colloids are essential building blocks for advanced materials.
  • Engineering complex colloidal structures with precise control remains a challenge.

Purpose of the Study:

  • To demonstrate the versatility of Capillary Assembly of Liquid Particles (CALP) for fabricating complex colloids.
  • To engineer geometrically diverse Janus and patchy colloids using CALP.

Main Methods:

  • Depositing emulsion particles into patterned microarrays within a fluidic cell.
  • Utilizing consecutive assembly and heterogeneous coassembly techniques.
  • Manipulating capillary immersion force, liquid particle hardness, and coalescence rate for lateral patterning.

Main Results:

  • Fabrication of eleven distinct colloid structures, including Janus squares and patchy particles.
  • Demonstration of bilayer and multi-material colloid assembly.
  • Engineered colloids exhibit fluorescence, resist flocculation, and are stable in organic solvents.

Conclusions:

  • CALP is a versatile microfabrication strategy for creating complex, arbitrarily shaped polymer colloids.
  • Heterogeneous CALP enables the synthesis of nonequilibrium particle structures not achievable with traditional wet chemistry.
  • These engineered colloids are promising for developing advanced nano/micromaterials and devices.