Designed Eu³⁺ functionalized Zr-MOF-808 probe for highly sensitive monitoring multiple dyes

Dyes detection remains a serious task because of their high toxicity. In present work, designed Eu³⁺ functionalized Zr-metal-organic framework (Eu³⁺@Zr-MOF-808) as fluorescent probe was constructed via post-synthetic modification (PSM) for rapid monitoring four most commonly used dyes (malachite green (MG), brilliant green (BG), alizarin red S (ARS), indigo red (IDR)). Systematic exploring on the sensing mechanism reveals that fluorescence resonance energy transfer (FRET) for BG, MG and IDR and inner filter effect (IFE) for ARS contribute to the realization of the fluorescence quenching process. It exhibits excellent sensing performances with low limit of detection (LOD) of 32, 58, 77 and 133 nM for BG, IDR, MG and ARS, respectively. The as-constructed Eu³⁺@Zr-MOF-808 was demonstrated to be a highly sensitive probe for screening of MG in fish pond and IDR in printing wastewater with satisfying results. Moreover, a portable test reagent bottle has been developed for visual on-site screening of sample containing dyes with naked eyes under UV light. This is the first attempt to construct the Eu³⁺@Zr-MOF-808 probe for sensingmultiple dyes in real samples and demonstrates promising applications in water quality monitoring.