Vapor-Phase Cyclohexene Epoxidation by Single-Ion Fe(III) Sites in Metal-Organic Frameworks

Heterogeneous catalysts supported on metal-organic frameworks (MOFs), which possess uniform porosity and crystallinity, have attracted significant interest for recent years due to the ease of active-site characterization via X-ray diffraction and the subsequent relation of the active site structure to the catalytic activity. We report the syntheses, structures, and oxidation catalytic activities of single-ion iron catalysts incorporated into the zirconium MOF NU-1000. Single-ion iron catalysts with different counteranions were anchored onto the Zr node through postsynthetic solvothermal deposition. Crystallographic characterization of the resulting MOFs (NU-1000-Fe-Cl and ) revealed that, while both frameworks have similar Fe coordination, the distance between Fe and the Zr₆ node differs significantly between the two. The product rate profiles of the two catalysts for vapor-phase cyclohexene epoxidation demonstrate different initial rates and product formations, likely originating from the different Fe-O distances.