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Related Concept Videos

Super-resolution Fluorescence Microscopy01:37

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Super-resolution fluorescence microscopy (SRFM) provides a better resolution than conventional fluorescence microscopy by reducing the point spread function (PSF). PSF is the light intensity distribution from a point that causes it to appear blurred. Due to PSF, each fluorescing point appears bigger than its actual size, and it is the PSF interference of nearby fluorophores that causes the blurred image. Various approaches to achieving higher resolution through SRFM have recently been...
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Related Experiment Video

Updated: Nov 20, 2025

Demonstration of Spin-Multiplexed and Direction-Multiplexed All-Dielectric Visible Metaholograms
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Solid-State Reversible Dual Fluorescent Switches for Multimodality Optical Memory.

Runqing Yang1, Yang Jiao1, Boyu Wang1

  • 1State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China.

The Journal of Physical Chemistry Letters
|January 26, 2021
PubMed
Summary
This summary is machine-generated.

Researchers developed dual fluorescent photoswitches using spiropyran (SP) and tetraphenylethene (TPE) derivatives. These solid-state switches offer reversible cyan and red fluorescence, enabling advanced optical applications.

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Area of Science:

  • Materials Science
  • Photochemistry
  • Organic Electronics

Background:

  • Fluorescent photoswitches are crucial for photonic devices and imaging.
  • Achieving reversible photoswitching in the solid state remains a challenge.

Purpose of the Study:

  • To develop novel solid-state fluorescent photoswitches with dual-color switching capabilities.
  • To investigate the structure-property relationships governing their reversible photoisomerization.

Main Methods:

  • Synthesis of spiropyran (SP)-functionalized tetraphenylethene (TPE) derivatives.
  • Spectroscopic analysis (UV-Vis absorption, fluorescence spectroscopy).
  • Theoretical calculations to understand molecular conformation and photoisomerization mechanism.

Main Results:

  • Demonstrated reversible dual fluorescence (cyan and red) in the solid state.
  • Achieved selective switching between states using alternating UV and visible light.
  • Identified that TPE's nonplanar structure facilitates SP photoisomerization via free volume.

Conclusions:

  • The developed TPE-SP derivatives exhibit excellent solid-state photoswitching properties.
  • These materials are promising for applications in anticounterfeiting and optical data storage.
  • The study highlights the importance of molecular design for solid-state photochromic materials.