MoS₂/Epitaxial graphene layered electrodes for solid-state supercapacitors

The potential of transition metal dichalcogenides such as MoS₂ for energy storage has been significantly limited so far by the lack of conductivity and structural stability. Employing highly conductive, graphitic materials in combination with transition metal dichalcogenides can address this gap. Here, we explore the use of a layered electrode structure for solid-state supercapacitors, made of MoS₂ and epitaxial graphene (EG) on cubic silicon carbide for on-silicon energy storage. We show that the energy storage of the solid-state supercapacitors can be significantly increased by creating layered MoS₂/graphene electrodes, yielding a substantial improvement as compared to electrodes using either EG or MoS₂ alone. We conclude that the conductivity of EG and the growth morphology of MoS₂ on graphene play an enabling role in the successful use of transition metal dichalcogenides for on-chip energy storage.