α-γ-Type [Mo₈O₂₆]^4--Containing Metal-Organic Complex Possessing Efficient Catalytic Activity toward the Oxidation of...

In this work, a new α-γ-type [Mo₈O₂₆]^4- anion was first synthesized and characterized by single-crystal X-ray diffraction analysis and was obtained by introducing molybdate to the synthesis of metal-organic complex (MOC) under hydrothermal conditions. An octamolybdate-based MOC, namely, {[Cu₈(H₂O)₆](dpyh)₄(α-γ-Mo₈O₂₆) }·(β-Mo₈O₂₆)·8.5H₂O (H₂dpyh = N,N-bis(3-pyrazolamide)-1,2-hexahydrobenzene), was obtained. The α-γ-type [Mo₈O₂₆]^4- anion was composed of four MoO₆ octahedra and four MoO₅ trigonal bipyramids by sharing their edges and corners. The title complex exhibited a 1D structure in which an α-γ-type [Mo₈O₂₆]^4- anion was connected with [Cu₄(dpyh)₂] units in a staggered manner. Under optimized conditions, complex 1 as the catalyst can achieve a highly efficient conversion (more than 99%) of thioanisole within 30 min and above 99% selectivity toward sulfoxide. Furthermore, efficient catalytic oxidation of thioether derivatives was also performed with 1 as the catalyst. In addition, the stable electrochemical sensing performance and adsorption capacity toward organic dyes were tested.