Recent advances in single-atom catalysts for advanced oxidation processes in water purification

Single-atom catalysts (SACs) have attracted considerable attention from researchers because of their distinct structures and characteristics, especially in maximizing atomic utilization and elevating the intrinsic catalytic activity. More recently, SACs have been becoming a burgeoning area of the environmental field and are extensively applied to remove various refractory organic pollutants. This review summarizes the emerging synthetic and characterization strategies of SACs and analyzes their development tendency. Besides, the application of SACs in advanced oxidation processes (AOPs, e.g., catalysis of H₂O₂, activation of persulfates and photocatalysis) is discussed. The excellent removal of pollutants depends on the fast generation of reactive oxygen species (SO₄^•-, ^•OH, ¹O₂, and O₂^•-). The advantages of SACs in AOPs are summarized, and constructive opinions are put forward for the stability and activity of the catalyst. Finally, the opportunities and challenges faced by SACs and its future development direction in the AOPs catalytic field are proposed.