Fabrication of antireflective silver-capped tin oxide nano-obelisk arrays as high sensitive SERS substrate

Hybrid noble metal-semiconductor oxide nanostructures often provide unique and synergetic functionalities that are highly desirable in various practical applications. However, the fabrication of such systems with desired functionalities using cost-effective techniques is still a great challenge. In this work, we report a facile route for the preparation of novel Ag/SnO₂ nano-obelisk arrayed thin films on silicon substrates by spray pyrolysis and thermal evaporation techniques. The prepared samples exhibited broadband antireflectance in both UV and visible regions attributed to the refractive index gradient and scattering provided by the nano-obelisk arrays. The localised surface plasmon resonance of silver nanocaps further enhanced the light absorption contributing to the antireflective property of the hybrid system. Ag/SnO₂ nano-obelisk arrayed thin film exhibited excellent SERS performance with an enhancement factor of 1.13 × 10⁸ with a limit of detection value of 10^-12 M for the trace detection of R6G dye. In addition, Ag/SnO₂ nano-obelisk arrayed thin film based SERS substrate exhibited good homogeneity across the measured spots and outstanding stability which are essential for quantitative field analysis. The results indicate that the Ag/SnO₂ nano-obelisk arrayed thin films are efficient SERS substrates with the merits of having the ease of production, high sensitivity and stability for various practical sensing applications.