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Capacitor With A Dielectric01:18

Capacitor With A Dielectric

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Parallel plate capacitors consist of two conducting plates separated by a certain distance. However, it is mechanically difficult to hold the large plates parallel to each other without actual contact. Hence, a dielectric layer is commonly placed between the plates, which provides an easy solution for holding the plates together with a small gap and increases the capacitance of the capacitor.
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
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Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

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Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
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Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

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The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
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Related Experiment Video

Updated: Nov 17, 2025

Sensitivity Enhancement of Soft Capacitive Pressure Sensors Using a Solvent Evaporation-Based Porosity Control Technique
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Sensitivity Enhancement of Soft Capacitive Pressure Sensors Using a Solvent Evaporation-Based Porosity Control Technique

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Dielectric Coatings for Resistive Pulse Sensing Using Solid-State Pores.

Tomoki Hayashida1, Makusu Tsutsui1, Sanae Murayama1

  • 1The Institute of Scientific and Industrial Research, Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047, Japan.

ACS Applied Materials & Interfaces
|February 17, 2021
PubMed
Summary

Dielectric coatings on solid-state pores control particle capture and movement. Modifying pore surface charge optimizes translocation dynamics for enhanced particle and molecule sensing.

Keywords:
dielectric coatingselectroosmotic flowionic currentresistive pulsetranslocation dynamics

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Chemistry

Background:

  • Solid-state nanopores are crucial for single-particle sensing.
  • Controlling particle dynamics within nanopores is key for sensing applications.
  • Surface properties of nanopores significantly influence particle interactions.

Purpose of the Study:

  • To systematically investigate the impact of dielectric coatings on particle capture and translocation dynamics in solid-state nanopores.
  • To explore how different dielectric materials alter the surface charge (ζ-potential) of nanopore walls.
  • To establish a method for engineering nanopore surfaces to optimize sensing performance.

Main Methods:

  • Fabrication of silicon nitride (SiN) membranes with solid-state nanopores.
  • Deposition of various dielectric coatings (SiO₂, HfO₂, Al₂O₃, TiO₂, ZnO) onto the nanopore surfaces.
  • Characterization of surface properties, including ζ-potential and isoelectric points.
  • Resistive pulse measurements using negatively charged polystyrene beads to analyze electrophoretic capture and translocation.

Main Results:

  • Dielectric coatings successfully modified the ζ-potential of the pore walls.
  • Increased negative surface potential at the oxide surface facilitated electrophoretic capture of particles.
  • Slower translocation of particles was observed in channels with a more negative electric potential.
  • The choice of dielectric coating material directly influenced the particle-surface interactions and translocation behavior.

Conclusions:

  • Dielectric coating is an effective strategy to tailor the capture-to-translocation dynamics of single particles in solid-state pores.
  • Engineering the nanopore surface charge through dielectric coatings allows for optimization of particle sensing.
  • These findings provide a framework for designing advanced nanopore sensors with improved sensitivity and resolution.