Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites

Cesium lead halides have intrinsically unstable crystal lattices and easily transform within perovskite and nonperovskite structures. In this work, we explore the conversion of the perovskite CsPbBr₃ into Cs₄PbBr₆ in the presence of PbS at 450 °C to produce doped nanocrystal-based composites with embedded Cs₄PbBr₆ nanoprecipitates. We show that PbBr₂ is extracted from CsPbBr₃ and diffuses into the PbS lattice with a consequent increase in the concentration of free charge carriers. This new doping strategy enables the adjustment of the density of charge carriers between 10¹⁹ and 10²⁰ cm^-3, and it may serve as a general strategy for doping other nanocrystal-based semiconductors.