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Updated: Nov 16, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Double-shelled carbon nanocages grafted with carbon nanotubes embedding Co nanoparticles for enhanced hydrogen
Xue-Zhi Song1, He Wang, Zhuoxi Li
1State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Panjin Campus, Panjin, 124221, China.
Abstract:
Herein, small Co nanoparticles (NPs) encapsulated in N-doped double-shelled carbon nanocages grafted with thin carbon nanotubes (Co@CNTs@DSCNCs) were synthesized from yolk-shell bimetallic zeolitic imidazolate framework (BMZIF). For HER electrocatalysis, they exhibit higher activity (η10 = 214 mV) and more favorable kinetics than Co@CNTs@PC (PC = porous carbon) with thick CNTs and large Co NPs derived from solid BMZIF cubes.
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