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Updated: Nov 15, 2025
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Structure-Property Relationship of Cellulose Nanocrystal-Polyvinyl Alcohol Thin Films for High Barrier Coating
Md Nuruddin1, Reaz A Chowdhury2, Ryan Szeto2
1Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, Michigan 48824, United States.
Abstract:
CO2 and O2 gas permeability are paramount concerns in food packaging. Here, the permeability of cellulose nanocrystals (CNCs) and polyvinyl alcohol (PVA) coatings was explored as it relates to varied CNC content. Specifically, this work focuses on the role of PVA in rheology and barrier performance of the CNC films. Results show that shear-casted CNC films are transparent and have a high-order parameter, which is attributed to the shear-thinning behavior of the CNCs. The barrier performance of the CNC films improved because of the synergistic effect of having both alignment of CNCs and a lower free volume. The CNC-PVA films exhibited excellent barrier performance as compared to traditional engineered polymers, even much higher than high barrier ethylene-vinyl alcohol copolymer films. Furthermore, the moisture sensitivity of the films was greatly diminished with the addition of PVA. Overall, the results show applicability of CNC-PVA coating formulations for high barrier packaging applications.
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