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Updated: Nov 14, 2025

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Synthesis and Electro-Optical Property of Green Fluorescent Emitter Based on Anthracene Core and Optimized Side
Seunghyun Kim1, Seokwoo Kang1, Jongwook Park1
1Department of Chemical Engineering, Kyung Hee University, Yongin-si, Gyeonggi-do, 17104, Republic of Korea.
Abstract:
New green emitter is designed and synthesized by selecting anthracene having high photoluminescence quantum yield (PLQY) and diphenylamine side group substituted methyl and t-butyl group: N9,N10-bis(5-(tert-butyl)-2-methylphenyl)-N9,N10-bis(2,4-dimethylphenyl)anthracene-9,10-diamine (3Me-1Bu-TPADA). Photophysical, electrochemical, and electroluminescent (EL) properties of 3Me-1Bu-TPADA were investigated. The maximum photoluminescence (PL) emission wavelengths of 3Me-1Bu-TPADA in solution and in a film were 528 nm and 531 nm, respectively. 3Me-1Bu-TPADA has excellent thermal properties with glass transition temperatures (Tg) of 110 °C, melting temperatures (Tm) of 217 °C of, and degradation temperature (Td) of 330 °C. 3Me-1Bu-TPADA was used as an emitting layer in non-doped devices: ITO/2-TNATA (60 nm)/NPB (15 nm)/3Me-1Bu-TPADA (30 nm)/Alq₃ (30 nm)/LiF (1 nm)/Al (200 nm). The 3Me-1Bu-TPADA device showed luminance efficiency of 6.05 cd/A, EQE of 2.68% at 10 mA/cm².
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