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Updated: Nov 14, 2025

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Preparation and Electrochemical Analysis of Ni-Based Metal Organic Frameworks Containing Binary Ligands for Capacitor
Hye-Jin Oh1, Yongju Jung2, Seok Kim1
1Department of Chemical and Biomolecular Engineering, Pusan National University, 2, Busandaehak-Ro 63 Beon-Gil, Geumjeong-Gu, Busan 46241, South Korea.
Abstract:
As one of the energy storage systems, supercapacitors have quite long charge-discharge cycle life. Among many kinds of electrode materials, metal organic frameworks (MOFs) have unique properties such as high specific surface areas and large pore volume as supercapacitor electrode materials. Nickel-MOFs consist of binary ligand such as 1,3,5-Trimesic acid (H₃BTC) and terephthalic acid (TPA) were used as working electrode materials in three electrode cell for capacitor system. When synthesizing MOFs, it is possible to prepare uniform crystals using hydrothermal synthesis. The morphology of composites was analyzed by field emission scanning electron microscopy (FE-SEM). Electrochemical properties were measured by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) in 6M KOH electrolyte.

