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Updated: Nov 12, 2025

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Published on: May 29, 2021
Effective screening of medium-assisted van der Waals interactions between embedded particles
Johannes Fiedler1, Michael Walter2, Stefan Yoshi Buhmann3
1Institute of Physics, University of Freiburg, Hermann-Herder-Str. 3, 79104 Freiburg, Germany.
Abstract:
The effect of an implicit medium on dispersive interactions of particle pairs is discussed, and simple expressions for the correction relative to vacuum are derived. We show that a single point Gauss quadrature leads to the intuitive result that the vacuum van der Waals C6-coefficient is screened by the permittivity squared of the environment evaluated near to the resonance frequencies of the interacting particles. This approximation should be particularly relevant if the medium is transparent at these frequencies. In this manuscript, we provide simple models and sets of parameters for commonly used solvents, atoms, and small molecules.

