A review on efficient removal of phthalic acid esters via biochars and transition metals-activated persulfate systems

As emerging contaminants, PAEs (Phthalic Acid Esters or Phthalate Esters) have been extensively utilized in industrial production to soften the rigid plastics (plasticizers), and their related products are widely distributed in our daily life. The PAEs can readily transfer from the products to the surrounding environment due to not being chemically bound to the products. In this study, we analyzed the PAEs' properties, usage, and consumption in the world, as well as toxicity to human beings. As endocrine-disrupting chemicals (EDCs), PAEs can disturb the normal hormones reactions, resulting in developmental and reproductive problems. Thus, we have to concern the removal strategies of PAEs. We summarized two novel approaches, including biochars and persulfate (PS) oxidation for effectively removing PAEs in the literature. Their characteristics, removal mechanisms, and the main impact factors on the removal of PAEs were highlighted. Moreover, transition metal-activated PS showed good performance on PAEs degradation. Furthermore, the synergy of biochars and transition metals-PS can overcome the disadvantages of a single approach, and show better performance on the removal of PAEs. Finally, we put forward vital strategies to update two approaches (including the combined) for enhancing the removal of PAEs. It is expected that the researchers or scientists can get a hint on effectively remediating PAEs-contaminated sites via the biochars' sorption/transition metals-PS or the combined two from this review paper.