High-Throughput NO Removal by Two-Stage Plasma Honeycomb Monolith Catalyst

A two-stage plasma catalyst system for high-throughput NO removal was investigated. Herein, the plasma stage involved the large-volume plasma discharge of humidified gas and was carried out in a sandwich-type honeycomb monolith reactor consisting of a commercial honeycomb catalyst (50 mm high; 93 mm in diameter) located between two parallel perforated disks that formed the electrodes. The results demonstrated that, in the plasma stage, the reduction of NO did not occur at room temperature; instead, NO was only oxidized to NO₂ and n-heptane to oxygenated hydrocarbons. The oxidation of NO and n-heptane in the honeycomb plasma discharge state was largely affected by the humidity of the feed gas. Furthermore, the oxidation of NO to NO₂ occurs preferably to that of n-heptane with a tendency of the NO oxidation to decrease with increasing feed gas humidity. The reason is that the generation of O₃ decreases as the amount of water vapor in the feed gas increases. Compared to the catalyst alone, the two-stage plasma catalyst system increased NO removal by 29% at a temperature of 200 °C and an energy density of 25 J/L.