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Updated: Nov 10, 2025
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Cocrystallization of Chiral 3d-4f Clusters {Mn10Ln6} and {Mn6Ln2}
Xing Wang1, Ming-Hao Du1, Han Xu1
1Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Abstract:
Cocrystallization of different metal nanoclusters facilitates the preparation of cluster-based nanomaterials with enhanced properties. Herein, two pairs of enantiomeric 3d-4f cocrystallization structures of clusters R/S-[Mn10Ln6] and R/S-[Mn6Ln2] (Ln = Dy for 1 and 1, Y for 2 and 2) have been reported. Compounds R/S-[Mn10Ln6][Mn6Ln2] exhibit a large optical activity and magneto-optic effect as verified by natural circular dichroism (NCD) and magnetic circular dichroism (MCD). In addition, alternating current (ac) magnetic measurements show that the chiral R/S-[Mn10Dy6][Mn6Dy2] cocrystallization structure displays slow magnetic relaxation with Ueff = 25.1 K.
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