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Development of Magnesium Anode-Based Transient Primary Batteries.

Jazer Jose H Togonon1,2, Eugene A Esparcia1, Julie Anne D Del Rosario1,2

  • 1Laboratory of Electrochemical Engineering (LEE), Department of Chemical Engineering, College of Engineering, University of the Philippines Diliman, Quezon City, 1101, Philippines.

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Summary

Researchers developed high-performance biodegradable transient batteries using common metals like magnesium and copper. The Mg-Cu anodized battery demonstrated excellent discharge performance, paving the way for advanced biodegradable electronics.

Keywords:
anodization processmagnesiummetal oxide cathodestransient batteries

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Biomedical Engineering

Background:

  • Biodegradable primary batteries, or transient batteries, are crucial for autonomous biodegradable electronic devices.
  • Developing high-performance, functional transient batteries is an ongoing challenge.

Purpose of the Study:

  • To investigate magnesium, copper, iron, and zinc as materials for biomedical transient electronic devices.
  • To evaluate different full cell combinations using these metals and phosphate buffered saline (PBS) as an electrolyte.

Main Methods:

  • Metals (Mg, Cu, Fe, Zn) were tested in various full cell configurations with PBS electrolyte.
  • Cathodes were formed by galvanostatic anodization of metal foils.
  • Electrochemical measurements were performed to assess full cell battery performance.

Main Results:

  • The Mg-Cu anodized chemistry achieved the highest power density at 0.99 mW/cm².
  • This chemistry showed a nominal operating voltage of 1.26 V initially, then 0.63 V.
  • Mg-Cu anodized exhibited the best discharge performance with a specific capacity of 2.94 mAh/cm².

Conclusions:

  • The Mg-Cu anodized transient battery demonstrates promising performance for biodegradable electronics.
  • This research contributes to the advancement of high-performance, functional biodegradable electronic devices.