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Updated: Nov 9, 2025
Physical, Chemical and Biological Characterization of Six Biochars Produced for the Remediation of Contaminated Sites
Published on: November 28, 2014
Optimization of biochar production based on environmental risk and remediation performance: Take kitchen waste for
Congbin Xu1, Xiao Tan2, Jiwei Zhao2
1Department of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China; College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 100049, PR China.
Abstract:
Two major obstacles that need to be addressed for environmental application of biochar include its environmental risk and remediation performance for target pollutants. In this study, kitchen waste was taken as an example to optimize the pyrolysis temperature for biochar production based on its heavy metal risk and Cd(II) remediation performance. The results showed that the pH and ash content of kitchen waste biochar (KWB) increased; however, the yield, H/C, and N/C decreased with increasing pyrolysis temperature. Total content of heavy metals in KWB got enriched after pyrolysis, while heavy metals' risk was reduced from moderate to low due to the transformation of directly toxic heavy metal fractions into potentially and/or non-toxic fractions. The equilibrium adsorption capacities of biochar for Cd(II) ranked as follows: 49.0 mg/g (600 °C), 46.5 mg/g (500 °C), 23.6 mg/g (400 °C), 18.2 mg/g (300 °C). KWB pyrolyzed at 500 °C was found to be the most suitable for green, efficient, and economic remediation of Cd(Ⅱ) contaminated water. SEM-EDS and XPS characterization results indicated that KWB removed Cd(II) via precipitation, complexation with carboxyl/hydroxyl, ion exchange with metal cations, and coordination with π-electrons. This study puts forward a new perspective for optimizing biochar production for environmental application.
