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Preparation and 3D Tracking of Catalytic Swimming Devices

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Macrocycles in Bioinspired Catalysis: From Molecules to Materials.

Jie Shang¹, Yao Liu², Tiezheng Pan¹

¹School of Life Sciences, Northwestern Polytechnical University, Xi'an, China.

Frontiers in Chemistry

|April 12, 2021

Summary

Macrocyclic compounds are key to supramolecular chemistry, enabling bioinspired catalysts. Recent advances show multilevel macrocycle catalysts with unique binding and catalytic sites.

Keywords:

catalysis cucurbituril cyclodextrin macrocycle porphyrin rotaxane

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Area of Science:

Supramolecular Chemistry
Catalysis
Materials Science

Background:

Macrocyclic compounds are extensively studied as host molecules in supramolecular chemistry.
Their structural features are crucial for molecular recognition, mimicking natural enzyme catalytic efficiency.
This makes macrocycles ideal scaffolds for designing bioinspired catalysts.

Purpose of the Study:

To review recent advancements in multilevel macrocycle catalysts.
To highlight catalysts with unique catalytic centers and substrate-binding affinities.
To cover progress from single-molecule systems to metal-organic frameworks.

Main Methods:

Literature review of recent research on macrocycle-based catalysts.
Analysis of single-molecule and metal-organic framework (MOF) materials.
Focus on catalytic centers and substrate-binding properties.

Main Results:

Demonstration of multilevel macrocycle catalysts across diverse material types.
Showcasing unique catalytic centers and substrate-binding affinities in these systems.
Highlighting advances from molecular to extended framework materials.

Conclusions:

Macrocycles are versatile building blocks for advanced bioinspired catalysts.
Multilevel macrocycle catalysts offer unique opportunities in catalysis.
Future research directions span single-molecule to MOF-based catalytic systems.