Cresting the Coulomb Barrier of Polyanionic Metal Clusters

Combining photoelectron spectroscopy with tunable laser pulse excitation allows us to characterize the Coulomb barrier potential of multiply negatively charged silver clusters. The spectra of mass- and charge-selected polyanionic systems, with z=2-5 excess electrons, show a characteristic dependence on the excitation energy, which emphasizes the role of electron tunneling through the barrier. By evaluating experimental data from an 800-atom system, the electron yield is parametrized with respect to tunneling near the photoemission threshold. This analysis results in the first experimentally based potential energy functions of polyanionic metal clusters.