Effects of nFe₃O₄ capping on phosphorus release from sediments in a eutrophic lake

This study applied the techniques of high-resolution dialysis (HR-Peeper) and diffusive gradients in thin films (DGT) to explore the effects and the behind mechanism for inhibition phosphorus (P) releasing from sediments by nFe₃O₄ capping. The highest decreasing rates of SRP and labile P (i.e., 49% and 47%, respectively) and the decreased flux of SRP showed that nFe₃O₄ capping can successfully control sediment internal P release. Adsorption by Fe(III) hydroxides with the oxidation of Fe(II) was one of the reasons for the decrease of P concentrations in nFe₃O₄ capping sediments. This was supported by the increase of Eh and significant negative correlation between Eh with Fe(II) (soluble and labile Fe(II)) and P (SRP and labile P) and significant positive correlation between Fe(II) and P in sediments by nFe₃O₄ capping. An outer-sphere complex between positively charged nFe₃O₄ surface groups and P formation was the other reason to decrease the concentrations of P in the nFe₃O₄ capping sediments. This was supported by the decrease of pH value in sediments by the capping of nFe₃O₄. This study shows that nFe₃O₄, when used as capping agent, can effectively control the sediment internal P release, which is expected to be used as a potential material for repairing lake eutrophication.