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Adsorption Device Based on a Langatate Crystal Microbalance for High Temperature High Pressure Gas Adsorption in Zeolite H-ZSM-5
Published on: August 25, 2016
Gating control effect facilitates excellent gas selectivity in a novel Na-SSZ-27 zeolite
Chao Zhao1, Jiamin Yuan2, Xiaomin Tang2
1School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China. wtliu@zzu.edu.cn and State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan, 430071, P. R. China. zqliu@wipm.ac.cn.
Abstract:
A novel Na-SSZ-27 zeolite was demonstrated to possess excellent H2/CO2 diffusion selectivity of more than 100. This investigation highlights the crucial effect of the "gating control" of the 8-ring windows on the separation, where sodium cations act as gates to selectively control the diffusion of CO2 and promote the selectivity for H2.
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