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Related Concept Videos

Resistivity01:22

Resistivity

4.1K
When a voltage is applied to a conductor, an electrical field is generated, and charges in the conductor feel the force due to the electrical field. The current density that results depends on the electrical field and the properties of the material. In some materials, including metals at a given temperature, the current density is approximately proportional to the electrical field. In these cases, the current density can be modeled as:
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Electrodes: Overview01:17

Electrodes: Overview

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 Electrochemical measurements are conducted in an electrochemical cell composed of various components that control and measure the current and potential. One fundamental component is electrodes, conductive materials that enable electron transfer reactions at their surfaces.
There are two main types of electrodes in electrochemical cells. The first type, known as the working or indicator electrode, has a potential that is sensitive to the analyte's concentration and reacts to changes in...
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Measurement of Air Content in Concrete01:23

Measurement of Air Content in Concrete

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Air content measurement in concrete is critical for ensuring structural integrity and durability of concrete structures, especially in environments prone to severe weather conditions. Accurate air content analysis optimizes concrete's resistance to freeze-thaw cycles and enhances its workability and strength. Several methods are standardized under ASTM guidelines to measure the air content in fresh concrete, each suitable for different concrete types and conditions.
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Electrical Conductivity01:13

Electrical Conductivity

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In perfect conductors, the electric field inside is always zero due to the abundance of free electrons, which nullify any field by flowing. As a result, any residual charge resides on the surface.
In a practical conductor, an applied electric field may be sustained, causing a flow of electrons, which produce a current. The differential form of the current, the current density, is related to the electric field.
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Potentiometry: Types of Electrodes01:19

Potentiometry: Types of Electrodes

1.2K
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
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Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

1.1K
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
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Dynamic Electrochemical Measurement of Chloride Ions
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An Embedded-Sensor Approach for Concrete Resistivity Measurement in On-Site Corrosion Monitoring: Cell Constants

Jose Enrique Ramón1, Isabel Martínez1, José Manuel Gandía-Romero2

  • 1Instituto de Ciencias de la Construcción Eduardo Torroja, CSIC, C/Serrano Galvache No.4, 28033 Madrid, Spain.

Sensors (Basel, Switzerland)
|April 30, 2021
PubMed
Summary

This study introduces a method to determine concrete electrical resistivity using electrical resistance measurements from a novel corrosion sensor. This allows for simultaneous monitoring of resistivity and corrosion rate in structural health monitoring.

Keywords:
durabilitynon-destructive techniquereinforced concreteresistivitysensorsteel corrosionstructure health monitoring

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Area of Science:

  • Materials Science
  • Civil Engineering
  • Electrochemistry

Background:

  • Concrete electrical resistivity is crucial for structural health monitoring and diagnosing reinforcement corrosion.
  • Existing methods for resistivity measurement can be complex and sensor-specific.

Purpose of the Study:

  • To develop a simple and reliable method for determining concrete electrical resistivity from electrical resistance measurements.
  • To create a versatile sensor cell constant applicable across different sensor implementations.
  • To enable simultaneous monitoring of resistivity and corrosion rate using a single embedded sensor.

Main Methods:

  • Developed a novel corrosion sensor integrated into the Integrated Network of Sensors for Smart Corrosion Monitoring (INESSCOM).
  • Proposed a simple expression to determine resistivity from concrete electrical resistance (RE).
  • Investigated key geometrical features of the sensor in calibration solutions to ensure universal cell constant validity.
  • Adapted potential step voltammetry (PSV) by adding a short potentiostatic pulse for RE measurement.

Main Results:

  • A simple expression was derived to reliably calculate concrete resistivity from RE.
  • The derived cell constants are valid for various sensor implementation scenarios.
  • A protocol was established to determine resistivity from PSV measurements, alongside corrosion rate.
  • The embedded-sensor approach facilitates simultaneous monitoring of resistivity and corrosion rate.

Conclusions:

  • The proposed method offers a reliable and simple approach to determine concrete electrical resistivity.
  • The universal cell constant and embedded-sensor design enhance the applicability of resistivity monitoring.
  • Simultaneous monitoring of resistivity and corrosion rate is achievable with a single sensor, improving structural health monitoring efficiency.