Study on the degradation of tetracycline in wastewater by micro-nano bubbles activated hydrogen peroxide

Recently, the micro-nano bubble (MB) technology has attracted people's attention due to its special advantages. Here, we carried out the technology of combining MB and hydrogen peroxide (MB/H₂O₂) to achieve efficient degradation of tetracycline wastewater. The effect of MB/H₂O₂ technology on the degradation efficiency of tetracycline was deeply analysed by investigating the reaction time, H₂O₂ dosage, pH and MB inlet flow. The results showed that the degradation rate of tetracycline hydrochloride by MB/H₂O₂ technology can reach 92.43%, which is 9.44 and 3.94 times that of MB and H₂O₂ alone. Through electron spin resonance (ESR) analysis and free radical quenching experiments, a possible mechanism for MB/H₂O₂ technology to efficiently degrade TC was proposed. In the MB/H₂O₂ system, the high temperature and high pressure environment generated when MB ruptures can activate H₂O₂ to obtain a higher number of active oxygen species. •OH is the main reactive oxygen radical in the process of MB/H₂O₂ degradation of TC, followed by HO₂•/•O₂-. In addition, the possible intermediate products of the oxidation TC process were identified by HPLC-MS technology. Under the action of •OH and HO₂•/•O₂- free radicals, TC molecules undergo demethylation and hydroxylation, ring-opening reactions, isomerization, deethylation, deacylation, deamination and dehydration reactions to generate intermediate products and finally convert them into CO₂ and H₂O. The development of MB/H₂O₂ technology can potentially be used to efficiently remove TC substances in the water environment and provide a new method for water purification.