A Bioinspired Molybdenum Catalyst for Aqueous Perchlorate Reduction

Perchlorate (ClO₄^-) is a pervasive, harmful, and inert anion on both Earth and Mars. Current technologies for ClO₄^- reduction entail either harsh conditions or multicomponent enzymatic processes. Herein, we report a heterogeneous ()Mo-Pd/C catalyst directly prepared from Na₂MoO₄, a bidentate nitrogen ligand (), and Pd/C to reduce aqueous ClO₄^- into Cl^- with 1 atm of H₂ at room temperature. A suite of instrument characterizations and probing reactions suggest that the Mo^VI precursor and at the optimal 1:1 ratio are transformed in situ into oligomeric Mo^IV active sites at the carbon-water interface. For each Mo site, the initial turnover frequency (TOF₀) for oxygen atom transfer from ClO^- substrates reached 165 h^-1. The turnover number (TON) reached 3840 after a single batch reduction of 100 mM ClO₄^-. This study provides a water-compatible, efficient, and robust catalyst to degrade and utilize ClO₄^- for water purification and space exploration.