Microstructural behavior of magnetorheological elastomer undergoing durability evaluation by stress relaxation
Mohd Aidy Faizal Johari1, Saiful Amri Mazlan2, Mohamed Mahmoud Nasef3
1Engineering Materials and Structures (eMast) ikhoza, Malaysia-Japan, International Institute of Technology (MJIIT), Universiti Teknologi Malaysia, 54100, Kuala Lumpur, Malaysia.
This study investigated magnetorheological elastomer (MRE) durability under stress relaxation. Researchers observed significant performance degradation linked to microstructural changes like molecular slippage and shear bands over an extended test duration.
Area of Science:
- Materials Science
- Polymer Science
- Mechanical Engineering
Background:
- Magnetorheological elastomers (MREs) are widely used, but their microstructural durability under stress is not well understood.
- Existing research lacks comprehensive experimental and theoretical data on MRE microstructural behavior, limiting their application.
- Understanding MRE microstructural durability is crucial for optimizing their performance and lifespan in various applications.
Purpose of the Study:
- To investigate the microstructural durability of magnetorheological elastomers (MREs) under prolonged stress relaxation.
- To identify and analyze the micro-mechanisms responsible for performance degradation in MREs during stress relaxation.
- To correlate observed microstructural phenomena with changes in viscoelastic properties.
Main Methods:
- Preparation of MRE samples using silicon rubber (SR) and 70 wt% carbonyl iron particles (CIP).
- Stress relaxation evaluation under torsional shear load with constant low strain (0.01%) within the linear viscoelastic (LVE) region.
- Microstructural analysis using Field Emission Scanning Electron Microscopy (FESEM) and Atomic Force Microscopy (AFM) in in-phase mode.
Main Results:
- MRE samples exhibited significant performance degradation over an 84,000-second test duration, the longest reported for MRE stress relaxation studies.
- Storage modulus decreased by 8.7%, normal force weakened by 27%, and stress performance reduced by 6.88%.
- Novel micro-mechanisms including molecular slippage, disentanglement, microplasticity, microphase separation, and shear band formation were identified as causes of performance depletion.
Conclusions:
- The study established a systematic correlation between microstructural deformation and the durability performance of MRE under stress relaxation.
- Identified microstructural phenomena provide insights into the viscoelastic property changes and degradation mechanisms in MREs.
- The findings contribute to a better understanding of MRE behavior, crucial for advancing their application in demanding environments.
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