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Updated: Nov 4, 2025

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
Published on: November 27, 2015
Hydrogen-Bonding-Induced Heterogenization of Nickel and Palladium Catalysts for Copolymerization of Ethylene with
Hu Zhang1, Chen Zou2, Huipeng Zhao1
1State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, P. R. China.
Abstract:
The practical synthesis of polar-functionalized polyolefins using transition-metal-catalyzed copolymerization of olefins with polar monomers is a challenge; the use of heterogeneous catalysts is little explored. Herein, we report the synthesis of heterogeneous naphthoquinone-based nickel (Ni/SiO2 ) and palladium (Pd/SiO2 ) catalysts through hydrogen bonding interactions of the ligands with the silica surface. Ni/SiO2 exhibits high activities (up to 2.65×106 g mol-1 h-1 ) during the copolymerization of ethylene with 5-hexene-1-yl-acetate, affording high-molecular-weight (Mn up to 630 000) polar-functionalized semicrystalline polyethylene (comonomer incorporation up to 2.8 mol %), along with great morphology control. The resulting copolymers possess improved surface properties and great mechanical properties. Pd/SiO2 can mediate ethylene copolymerization with polar monomers with moderate activity to produce high-molecular-weight copolymers with tunable comonomer incorporation.
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