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Updated: Nov 4, 2025
Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
Published on: July 9, 2015
In situ creation of multi-metallic species inside porous silicate materials with tunable catalytic properties
Yang-Yang Liu1, Guo-Peng Zhan1, Chuan-De Wu1
1State Key Laboratory of Silicon Materials, Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China. cdwu@zju.edu.cn.
Abstract:
Porous metal silicate (PMS) material PMS-11, consisting of uniformly distributed multi-metallic species inside the pores, is synthesized by using a discrete multi-metal coordination complex as the template, demonstrating high catalytic activity and selectivity in hydrogenation of halogenated nitrobenzenes by synergistically activating different reactant molecules via Ni and Co transition metal centers, while GdIII Lewis acid sites play a role in tuning the catalytic properties.
