Crystallization, Mechanical, and Antimicrobial Properties of Diallyl Cyanuric Derivative-Grafted Polypropylene

A functional N-halamine precursor with double bonds, 1-3-diallyl-s-triazine-2,4,6-trione (DTT), was synthesized and grafted onto polypropylene using dicumyl peroxide (DCP) as an initiator via melt blending at 200 °C. The DTT content grafted onto the polypropylene (PP) backbone was depended on both DTT and DCP concentrations in feed. The crystallization temperature of PP increased from 116 °C (neat PP) to 123 °C (10% DTT) with the increasing DTT content. Meanwhile, the crystallization rate and relative crystallinity of PP were significantly increased after introduction of the N-halamine precursor. Moreover, the incorporation of DTT had partial compensation for the decreasing mechanical properties of polypropylene, which resulted from degradation. When the amount of added DTT reached up to 5%, the chlorinated DTT-modified PP sheets were able to kill 10^5-6 cfu/mL Escherichia coli (CMCC 44103) and Staphylococcus aureus (ATCC 6538) within 10 min. The DTT-modified PP with the regenerating antibacterial property may have great potential for application in packaging, filters, and hygienic products.