Novel Three-Dimensional Graphene-Like Networks Loaded with Fe₃O₄ Nanoparticles for Efficient Microwave Absorption

A novel three-dimensional graphene-like networks material (3D-GLN) exhibiting the hierarchical porous structure was fabricated with a large-scale preparation method by employing an ion exchange resin as a carbon precursor. 3D-GLN was first studied as the effective microwave absorbing material. As indicated from the results of the electromagnetic parameter tests, and the minimum reflection loss (R_L) of the 3D-GLN reached -34.75 dB at the frequency of 11.7 GHz. To enhance the absorption performance of the nonmagnetic 3D-GLN, the magnetic Fe₃O₄ nanoparticles were loaded on the surface of the 3D-GLN by using the hydrothermal method to develop the 3D-GLN/Fe₃O₄ hybrid. The hybrid exhibited the prominent absorbing properties. Under the matching thickness of 3.0 mm, the minimum R_L value of hybrid reached -46.8 dB at 11.8 GHz. In addition, under the thickness range of 2.0-5.5 mm, the effective absorption bandwidth (R_L < 10 dB) was 13.0 GHz, which covered part of the C-band and the entire X-band, as well as the entire Ku-band. The significant microwave absorption could be attributed to the special 3D network structure exhibited by the hybrid and the synergistic effect exerted by the graphene and the Fe₃O₄ nanoparticles. As revealed from the results, the 3D-GLN/Fe₃O₄ hybrid could be a novel microwave absorber with promising applications.