Fabrication of self-assembled 0D-2D Bi₂MoO₆-g-C₃N₄ photocatalytic composite membrane based on PDA intermediate...

A Self-cleaning surface can efficaciously solve the problem of irreversible contamination buildup on filtration membranes. Photocatalytic membranes were fabricated via vacuum assisted layer-by-layer (LBL) self-assembly of 0D-2D Bi₂MoO₆-g-C₃N₄ on a PDA coated thin-film composite PVDF substrate by Schiff base reaction. The rejection rate of the simulated polysaccharide was more than 90%, and that of the simulated protein was more than 80%. The combination of the membrane and the photocatalyst promoted the degradation of tetracycline hydrochloride by the composite membrane to 67.85% when original membranes had minor effect. Under visible light, reversible radiation pollutants (R_r) gradually replaced irreversible pollutants (R_ir) as the main pollutants. The flux recovery ratio (FRR) of 0D-2D Bi₂MoO₆-g-C₃N₄/PVDF membrane was 85% after being irradiated with visible light for 30 min. The flux recovery rate of contaminated photocatalytic membrane remained 75%, and the rejection was maintained in a stable range after four cycles of the cleaning operation under visible light. The results indicated that the excellent photocatalytic performance of 0D-2D Bi₂MoO₆-g-C₃N₄ photocatalysis material and the increase of multi-dimensional functional layer morphology on pollutant contact area improved the mechanical stability, interception performance and self-cleaning performance of the composite membrane. This work not only builds a new type of composite coating membranes, but also help us to further understand the relationship between the dimensions of photocatalytic materials and the improvement of photocatalytic membrane performance.