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Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

36.3K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
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Intermolecular Forces03:13

Intermolecular Forces

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Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
65.2K
Intermolecular Forces and Physical Properties02:56

Intermolecular Forces and Physical Properties

24.5K
24.5K
Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

48.2K
Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
48.2K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility02:34

Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility

48.4K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
48.4K
Intermolecular vs Intramolecular Forces03:00

Intermolecular vs Intramolecular Forces

93.0K
Intermolecular forces (IMF) are electrostatic attractions arising from charge-charge interactions between molecules. The strength of the intermolecular force is influenced by the distance of separation between molecules. The forces significantly affect the interactions in solids and liquids, where the molecules are close together. In gases, IMFs become important only under high-pressure conditions (due to the proximity of gas molecules). Intermolecular forces dictate the physical properties of...
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Updated: Nov 2, 2025

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
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Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry

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7Li intermolecular multiple-quantum coherences in liquids.

Stefan Benders1, Alexej Jerschow1

  • 1Department of Chemistry, New York University, New York, NY 10003, United States.

Journal of Magnetic Resonance (San Diego, Calif. : 1997)
|June 8, 2021
PubMed
Summary

Researchers observed novel lithium-7 multiple-quantum coherences in aqueous solutions. These intermolecular effects show nonlinear concentration dependence, impacting electrochemical studies and enabling new lithium probe applications.

Keywords:
Dipolar demagnetizing fieldsIntermolecular multiple-quantum coherencesLithiumMultiple-quantum coherencesPulsed field gradients

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Area of Science:

  • Nuclear Magnetic Resonance Spectroscopy
  • Physical Chemistry
  • Electrochemistry

Background:

  • Conventional multiple-quantum coherences (MQCs) are typically observed under specific conditions related to alignment or quadrupolar relaxation.
  • Lithium ion solutions are crucial for understanding electrochemical systems, but their NMR interpretation can be complex.
  • The behavior of lithium ions in aqueous solutions requires further investigation, especially concerning complex coherence phenomena.

Purpose of the Study:

  • To report the observation of 7Li multiple-quantum coherences (MQCs) in aqueous solutions.
  • To characterize these MQCs outside conventional observation regimes.
  • To explore the implications of these findings for electrochemical studies and potential new applications.

Main Methods:

  • Nuclear Magnetic Resonance (NMR) spectroscopy was employed to study 7Li in aqueous solutions.
  • Experimental conditions were varied to observe MQCs beyond those typically associated with alignment or quadrupolar relaxation.
  • Concentration-dependent nonlinear behavior of the observed coherences was analyzed.

Main Results:

  • Evidence for the generation of 7Li MQCs was observed in aqueous solutions.
  • These coherences were detected outside the regimes of conventional alignment- or quadrupolar relaxation-induced MQCs.
  • A nonlinear dependence of these effects on lithium ion concentration was identified, indicating intermolecular origins.

Conclusions:

  • The observed 7Li MQCs are identified as intermolecular multiple-quantum coherences (iMQCs).
  • Awareness of these iMQCs is critical for accurate interpretation of NMR data in lithium ion solutions, particularly in electrochemistry.
  • These findings may pave the way for novel applications utilizing lithium as a spectroscopic probe.