Synthesis of Ultrathin and Grid-Structural Carbon Nanosheets Coupled with Mo₂ C for Electrocatalytic Hydrogen Production

Molybdenum carbide possessing a Pt-like d-band electronic structure is considered as one of potential candidates of electrocatalysts and it shows intrinsic catalytic property. However, a high carbonizing temperature easily leads to the coalescence of nanoparticles (NPs). Here, we propose a simple sol-gel route to achieve high dispersity of carbide NPs by designing a Mo-involved xerogel. The results show that molybdenum carbide NPs are dispersed and anchored on the nitrogen-doped carbon nanosheets (Mo₂ C@NC). Ultrathin carbon layers resemble graphene and the network structures act as a support of carbide NPs, which can hinder NPs' coalescence effectively. Nanpoparticles cross-coupled on network-structure nanosheets display the grid shapes. Electrochemical studies indicate that Mo₂ C@NC material exhibits outstanding hydrogen evolution performance in alkaline electrolyte.